ASTM A335 P5
Alloy seamless pipes
High-pressure boiler tubes are designed for use in boilers where steam or water is produced under high pressure.
Download PDFThese tubes are typically made from high-strength materials like carbon steel or alloy steel to withstand extreme temperatures and pressures. They are used in power plants, industrial boilers, and steam generators. The tubes are essential for the safe and efficient operation of high-pressure systems, as they prevent leakage and maintain the integrity of the boiler. Their quality and specifications must adhere to strict industry standards, such as ASTM and ASME.
The major way to improve power generation efficiency is to increase steam pressure and temperature in thermal power plant. Below is a table for relation between steam parameter, efficiency and coal consumption.
| Power generation unit | Steam pressure (MPa) | Steam temperature (°C) | Boiler efficiency (%) | Coal consumption (g/kW*h) |
| Medium pressure | 3.5 | 435 | 27 | 460 |
| High pressure | 9.0 | 510 | 33 | 390 |
| Ultra-high pressure | 13.0 | 535/535 | 35 | 360 |
| Subcritical | 17.0 | 540/540 | 38 | 324 |
| Supercritical | 25.0 | 567/567 | 41 | 300 |
| Ultra-supercritical | 30.0 | 600/600/600 | 48 | 256 |
From the above table, it can be seen that as steam pressure and temperature increase, power generation efficiency increases significantly while coal consumption decreases significantly. The technical challenge in improving steam parameters is the pressure and temperature resistance of boiler tubes. Pressure parts such as water wall, superheater, reheater, steam header and piping, which operate under harsh conditions, are our main concern in selecting suitable boiler tubes.
Waterwall tubes are integral components of a boiler's waterwall, forming the furnace walls where heat from the combustion process is transferred to the water inside the tubes. These tubes absorb heat, converting water into steam, which is then used to generate power. Waterwall tubes are made from high-strength materials to withstand extreme temperatures and pressures. They are crucial for the boiler's efficiency, providing thermal insulation and protecting the furnace from heat damage. These tubes are commonly used in power plants and industrial boilers.
Waterwall tube needs to have certain strength under room temperature and high temperature, good resistance to fatigue, flue gas corrosion and abrasion. It should also have good processing property, especially weldability.
Typically, membrane waterwall is used in supercritical (SC) and ultra-supercritical (USC) boilers. Due to the size and structure of waterwall panel, post-weld heat treatment is impossible inside furnace. Therefore, the weldability of selected waterwall tube is crucial. Additionally, medium inside waterwall tube is steam & water mixture in two phase, and outer wall of tubes is exposed in area where coal particles have the highest velocity inside combustion furnace. Issues related to fouling-induced temperature rise on tube wall and particle erosion during combustion must be considered when selecting material for waterwall tube.
Superheater and reheater of high pressure boilers operate under the most severe conditions. The tubes must meet the requirements of both creep strength and endurance strength while providing resistance to flue gas corrosion and fly ash erosion on the outer wall of the tubes, and resistance to steam oxidation on the inner wall, as well as good processing property and weldability.
In cases of boilers fired by low sulfur coal, from the perspective of creep strength, T91 tubes are suitable for superheater and reheater in SC and USC boilers when the tube wall temperature is ≤600°C. When the tube wall temperature is ≤620°C, T92, T122, and E911 tubes can be used. When the wall temperature is ≤650°C, NF12 and SAVE12 tubes can be used.
In cases of boilers fired by high sulfur coal, when the tube wall temperature is ≥600°C (steam temperature ≥566°C), austenitic heat-resistant steel such as TP304H, TP321H, TP316H, and TP347H should be selected for superheater and reheater tubes.
Superheater tubes are used in boilers to raise the temperature of steam beyond its saturation point, producing superheated steam. This superheated steam is then directed to steam turbines, improving the overall efficiency of power generation systems. These tubes must withstand extremely high temperatures and pressures, requiring materials that offer exceptional heat resistance and durability.
Reheater tubes are used to reheat steam that has passed through the turbine, restoring its energy for further use in the turbine. This reheating process enhances the efficiency of power generation by ensuring that the steam maintains sufficient energy for subsequent stages of power production. Like superheater tubes, reheater tubes are made from materials that can endure high temperatures and pressures.
Steam header and pipeline tubes are vital components in steam distribution systems. The steam header collects steam from the boiler and distributes it through the pipeline tubes to various points of use. These tubes must withstand high pressures and temperatures, ensuring efficient and safe steam flow. Typically made from carbon steel, alloy steel, or stainless steel, these tubes are designed to prevent steam leakage and maintain system integrity, making them essential in power plants, refineries, and industrial boilers.
As the steam headers and piping are not exposed to flue gas, their wall temperature is close to the steam temperature. This requires that the steel used has sufficient creep strength, fatigue strength, steam oxidation resistance, good workability and weldability.
Due to the low coefficient of thermal expansion and high thermal conductivity of ferritic refractory steels, they will not cause severe fatigue damage to the header and piping under high start-up and shut-down rates. Therefore, ferritic refractory tubes are the preferred materials.
For steam headers and piping of SC and USC boilers, P91 tubes can be selected when the tube wall temperature is ≤600°C. When the temperature is ≤620°C, P92, P122 and E911 tubes can be used. If the temperature is ≤650°C, NF12 and SAVE12 tubes can be selected.
Boiler tube 20G is a high-quality low-alloy steel commonly used in high-pressure boiler systems. This material is known for its excellent mechanical properties, weldability, and corrosion resistance, making it ideal for manufacturing various boiler components such as water wall pipes, economizer pipes, superheater pipes, and reheater pipes in power plants. The 20G boiler tube is designed to withstand high temperatures and pressures, conforming to the Chinese GB/T 5310 standards for seamless steel tubes used in high-pressure boilers.
Boiler tube 20G (National Standard GB5310, equivalent to DIN ST45.8, JIS STB42, ASME SA106B) is the most widely used steel whose chemical composition and mechanical properties are basically the same as 20#. 20G pipe has good strength at medium & high temperatures. Its low carbon content gives it good plasticity and toughness. Its hot & cold forming and welding performance is good.
20G boiler tube is mainly used to produce high pressure, SC and USC boiler parts such as superheater, reheater, economiser and water wall, etc. As graphitisation occurs in carbon steel after long-term operation at a temperature above 450°C, the temperature limit of 20G tube is better to be lower than that. Within this range, 20G tube can meet the material requirement for superheater and piping, and has good oxidation resistance, plasticity, toughness and weldability.
ASME SA106C tube is a high-temperature, seamless carbon steel pipe used in applications that involve extreme heat and high pressure, such as in power plants, refineries, and chemical industries. The "C" grade indicates a higher carbon content, providing greater tensile strength and heat resistance compared to grades A and B. ASME SA106C tubes are commonly used in boiler systems, heat exchangers, and pressure vessels where durability and performance under stress are critical. They meet the strict standards set by the ASME (American Society of Mechanical Engineers).
SA106C is a seamless carbon steel tube for high temperature applications. Its chemical composition is similar to 20G, but C and Mn content is higher, so yield strength is about 12% higher, while plasticity and toughness are acceptable. It could reduce tube wall thickness by about 10% if used to make steam headers instead of 20G. This could save some material cost, reduce welding work and reduce stress on the steam header during boiler start-up.
ASME SA209 tube is a specification covering seamless carbon-molybdenum alloy-steel tubes designed for high-temperature service. These tubes are primarily used in boiler systems, heat exchangers, and other pressure applications where elevated temperatures are common. The molybdenum content in SA209 tubes enhances their strength and heat resistance, making them suitable for environments where durability and performance are critical. These tubes are manufactured according to strict ASME (American Society of Mechanical Engineers) standards, ensuring high quality and reliability in demanding industrial applications.
SA209 Grade T1a (called 20MoG in China) is an alloy steel seamless boiler pipe. As it contains Mo element, its heat resistance performance is better than carbon steel. It tends to graphitisation under high temperature in long-term operation. SA-209 grade T1a could be used to produce water wall, superheater and reheater, the tube wall temperature should not exceed 510°C.
ASME SA210C tube is a seamless medium-carbon steel tube used primarily in boiler and superheater applications where high pressure and temperature are common. The "C" grade in SA210C indicates a higher carbon content, which provides greater strength and hardness, making it suitable for more demanding service conditions compared to other grades in the SA210 series. These tubes are manufactured according to the stringent standards of the American Society of Mechanical Engineers (ASME), ensuring high quality and durability in high-temperature environments.
SA210C (called 25MnG in China) is a pearlitic heat resistant steel that could be used as a small diameter boiler tube. Its chemical composition is similar to that of 20G, except that the C and Mn contents are higher. So its yield strength is about 20% higher than 20G, while plasticity and toughness are quite close to 20G. It could thin tube wall thickness, reduce material consumption and improve heat transfer when used to replace 20G. SA210C tube is mainly used to manufacture water wall, economiser, superheater which works under temperature lower than 500°C.
15CrMoG tube is a seamless alloy steel tube primarily used in high-pressure and high-temperature applications such as boilers and power plants. The "15CrMoG" designation indicates the tube is made from steel containing 15% chromium and molybdenum, which enhances its strength, heat resistance, and corrosion resistance. These properties make it ideal for use in harsh environments where durability and reliability are critical. 15CrMoG tubes conform to Chinese GB standards and are widely used in the manufacturing of superheaters, headers, and steam pipelines.
15CrMoG boiler tube has good heat resistance below 500~550°C. Graphitisation will not occur within this range in long-term operation. When the temperature exceeds this limit, its heat resistance will decrease significantly. 15CrMoG is mainly used to produce superheater, steam header and piping, etc.
The ASME SA213 T22 and SA335 P22, along with the 12Cr2MoG tube, are materials used in high-temperature applications, such as power plants and petrochemical industries.
SA213 T22 and SA335 P22 tubes are equivalent to Chinese grade 12Cr2MoG. It has relatively higher heat resistance among Cr-Mo series steels. T22 (P22) pipe has even higher fatigue strength and allowable stress than 9Cr-1Mo at the same temperature. Therefore, it is widely used in thermal power plants, nuclear power plants and pressure vessels abroad. But it's not as economical as 12Cr1MoVG, so it's not widely used in thermal power plants built in China. T22 (P22) tube is not sensitive to heat treatment and has good plasticity and weldability. Small diameter T22 tubes are mainly used for superheaters and reheaters where the tube wall temperature is ≤580°C, while large diameter P22 tubes are mainly used for steam headers and pipelines where the tube wall temperature is ≤565°C.
The 12Cr1MoVG tube is a type of alloy steel tube used primarily in high-temperature applications.
12Cr1MoVG tube is widely used to manufacture superheater, steam header and piping for high pressure, ultra-high pressure, subcritical boiler in China. It is a low-carbon, low-alloy pearlite heat-resistant steel. Its total alloy content is less than 2%, only half that of 2.25Cr-1Mo, but its fatigue strength is 40% higher after 100,000 hours of operation at 580°C.
ASME SA213 T91 and ASME SA335 P91 are both types of alloy steel tubes designed for high-temperature and high-pressure applications, such as in power generation and petrochemical industries.
T91 (P91) is a ferritic heat-resistant alloy steel pipe developed on the basis of T9 (9Cr-1Mo) with the addition of 0.030-0.070% N, 0.18-0.25% V, 0.06-0.10% Nb. 9% Cr content makes its oxidation resistance, corrosion resistance, high temperature strength and non-graphitisation tendency better than low alloy steel. 1% Mo content is to improve the high temperature strength and reduce the hot shortness of Cr steel. Compared with T9 pipe, it has better weldability and thermal fatigue performance, 3 times the fatigue strength under 600°C, and retains its excellent high temperature resistance. Compared with TP304 austenitic stainless steel, it has small expansion coefficient, good thermal conductivity and fatigue strength. It is mainly used for superheater and reheater working under 650°C.
ASME SA213 T92 is a type of alloy steel tube used primarily in high-temperature applications.
Like T91, T92 tube has better expansion coefficient, thermal conductivity, excellent fatigue strength, high tensile strength, good toughness and weldability. Its fatigue strength and permissible stress are 1.6 times that of T91, while its weldability and steam oxidation resistance are almost the same as those of T91.
T92 tube could partially replace TP304H and TP347H to manufacture for subcritical, supercritical, ultra-supercritical boiler pressure parts such as superheater, reheater whose tube wall temperature is less than 650°C.
The physical properties of high pressure boiler tubes are critical for its performance in high-temperature and high-pressure applications.
| Standard | Grade | Tensile strength (MPa) | Yield strength (MPa) | Elongation (%) | Hardness |
| GB5310 | 20G | 410~550 | ≥245 | ≥24 | -- |
| 20MnG | ≥415 | ≥240 | ≥20 | -- | |
| 25MnG | ≥485 | ≥275 | ≥24 | -- | |
| 15CrMoG | 440~640 | ≥235 | ≥22 | -- | |
| 12Cr2MoG | 450~600 | ≥280 | ≥20 | -- | |
| 12Cr1MoVG | 470~640 | ≥255 | ≥21 | -- | |
| 12Cr2MoWVTiB | 540~735 | ≥345 | ≥18 | -- | |
| 10Cr9Mo1VNb | ≥585 | ≥415 | ≥20 | -- | |
| ASME SA210 | SA210A-1 | ≥415 | ≥255 | ≥30 | ≤143HB |
| SA210C | ≥485 | ≥275 | ≥30 | ≤179HB | |
| ASME SA213 | SA213 T11 | ≥415 | ≥205 | ≥30 | ≤163HB |
| SA213 T12 | ≥415 | ≥220 | ≥30 | ≤163HB | |
| SA213 T22 | ≥415 | ≥205 | ≥30 | ≤163HB | |
| SA213 T23 | ≥510 | ≥400 | ≥20 | ≤220HB | |
| SA213 T91 | ≥585 | ≥415 | ≥20 | ≤250HB | |
| SA213 T92 | ≥620 | ≥440 | ≥20 | ≤250HB |
With years of expertise, we provide a diverse array of steel tube processing options. From sawing and machining tube blanks to intricate bending and upsetting operations, we actively assist you throughout your projects.
Our capabilities extend to eccentricity reduction and concentricity enhancement through turning and grinding. We excel in creating complex geometries using processes like rotary swaging and axial forming. Additionally, we offer property modifications via partial heat treatment, ensuring tailored solutions for your specific needs.
Alloy steel pipes are ideally suitable for chemical, petrochemicals, and other energy-related applications.
The alloy steel pipe adopts high quality carbon steel, alloy structural steel and stainless & heat resisting steel as raw material through hot rolling or cold drawn to be made.
Alloy steel can be used in process area where carbon steel has limitation such as
As an important element of steel products, alloy steel pipe can be divided into seamless steel pipe and welded steel pipe according to the manufacturing technique and tube billet shape.
Here you can see the common alloy steel grade that you will come across.
Why the application of alloy steel pipe is wider than others
There are many kinds of materials used for transport in industrial production. Specifically we will have more choices and it is not limited to the use of alloy steel pipe. But even in the face of more choices, many people tend to choose alloy steel pipe. People make their own choices will have their own reasons. This means the alloy steel pipe application has its own advantages. Compared with transmission lines made of other materials, after it meets the basic application requirements, its quantity is lighter. Then in the practical application of alloy steel pipe, it will have more advantages because of this. Besides its physical characteristic advantage, it also has economic advantages. The wide application of alloy steel pipe is with kinds of reasons. So in practical usage, we can exploit the advantages to the full, in this way can we get more profits in these applications of alloy steel pipe.
The transportation of kinds of gases or liquids in production needs to rely on alloy steel pipe. This shows that the actual role of alloy steel pipe application is important. High temperature resistant and low temperature resistant is the tolerance of temperature. In the practical application of alloy steel pipe, there will be many materials need to be transported. However their temperatures are not the same. So this can be the basic requirement to alloy steel pipe. It needs more corrosion resistance. Corrosion resistant material is the best material during transporting, because it is corrosion resistant. So it can be used in more occasions. And it is definitely very convenient for users.
Can be 100% recycled, environmentally friendly, energy-saving, resource conservation, national strategy, national policy to encourage the expansion of the field of application of high-pressure alloy pipe. Of alloy steel pipe total consumption accounted steel in the proportion is only half of the developed countries, to expand the field of use of the alloy steel pipe to provide a wider space for the development of the industry. The future needs of the average annual growth of China’s high-pressure alloy steel pipe long products up to 10-12%.
Alloy Steel pipe contains substantial quantities of elements other than carbon such as nickel, chromium, silicon, manganese, tungsten, molybdenum, vanadium and limited amounts of other commonly accepted elements such as manganese, sulfur, silicon, and phosphorous.
Our team of experienced sales specialists proudly partners with gas and chemical processors, power generation plants, oil refineries, and related industries to offer piping components and value-added services.
The biggest advantages of alloy steel pipe can be 100% recycled, environmentally friendly, energy-saving, resource conservation, national strategy, national policy to encourage the expansion of the field of application of high-pressure alloy pipe. Of alloy tube total consumption accounted steel in the proportion is only half of the developed countries, to expand the field of use of the alloy tube to provide a wider space for the development of the industry. According to the Chinese Special Steel Association alloy pipe Branch Expert Group, the future needs of the average annual growth of China’s high-pressure alloy pipe long products up to 10-12%.
Chemical composition inspection, mechanical properties test(tensile strength,yield strength, elongation, flaring, flattening, bending, hardness, impact test), surface and dimension test,no-destructive test, hydrostatic test.
identification of the chemical composition of the metal used to manufacture the fitting. Uses PMI sensors, including X-ray fluorescence or optical emission spectrometry.
Steel pipe delivery status(condition): cold / hard (BK), cold / soft (BKW), after cold stress relief annealing (BKS), annealing (GBK), normalized (NBK).
| Term | Symbol | Explanation |
|---|---|---|
| Cold-finished/hard (cold-finished as-drawn) | BK | No heat treatment after the last cold-forming process. The tubes therefore have only low deformability. |
| Cold-finished/soft (lightly cold-worked) | BKW | After the last heat treatment there is a light finishing pass (cold drawing) With proper subsequent processing, the tube can be cold-formed (e.g. bent, expanded) within certain limits. |
| Annealed | GBK | After the final cold-forming process the tubes are annealed in a controlled atmosphere or under vacuum. |
| Normalized | NBK | The tubes are annealed above the upper transformation point in a controlled atmosphere or under vacuum. |
The general cold strip mills, volume should go through continuous annealing (CAPL unit) to eliminate cold hardening and rolling stress, or batch annealing reach the mechanical properties of the corresponding standard specifies. Cold rolled steel surface quality, appearance, dimensional accuracy better than hot-rolled plate, and right-rolled thin product thickness is about 0.18mm, so the majority of users favor.
Cold rolled steel coil substrate products deep processing of high value-added products. Such as electro-galvanized, hot dip galvanized, electro-galvanized fingerprint resistant, painted steel roll damping composite steel, PVC laminating steel plates, etc., so that the excellent quality of these products has a beautiful, high resistance to corrosion, has been widely used.
Cold rolled steel coil finishing after annealing, cut the head, tail, trimming, flattening, smooth, heavy volume, or longitudinal clipboard. Cold-rolled products are widely used in automobile manufacturing, household electrical appliances, instruments, switches, buildings, office furniture and other industries. Steel plate strapping package weight of 3 to 5 tons. Flat sub-volume typically 3 to 10 tons / volume. Coil diameter 6m.
Bare packing/bundle packing/crate packing/wooden protection at the both sides of tubes and suitably protected for sea-worthly delivery or as requested.
There are probably hundreds of different methods for packing a pipe, and most of them have merit, but there are two principles that are vital for any method to work prevent rusting and Sea transportation security.
Our packing can meet any needs of the customers.
Our team of experienced sales specialists proudly partners with gas and chemical processors, power generation plants, oil refineries, and related industries to offer piping components and value-added services.
Alloy steels are made by combining carbon steel with one or several alloying elements, such as manganese, silicon, nickel, titanium, copper, chromium and aluminum. These metals are added to produce specific properties that are not found in regular carbon steel. The elements are added in varying proportions (or combinations) making the material take on different aspects such as increased hardness, increased corrosion resistance, increased strength, improved formability (ductility); the weldability can also change.
Commonly used alloying elements and their effects are listed in the table given below.
| Alloying Elements | Effect on the Properties |
|---|---|
| Chromium | Increases Resistance to corrosion and oxidation. Increases hardenability and wear resistance. Increases high temperature strength. |
| Nickel | Increases hardenability. Improves toughness. Increases impact strength at low temperatures. |
| Molybdenum | Increases hardenability, high temperature hardness, and wear resistance. Enhances the effects of other alloying elements. Eliminate temper brittleness in steels. Increases high temperature strength. |
| Manganese | Increases hardenability. Combines with sulfur to reduce its adverse effects. |
| Vanadium | Increases hardenability, high temperature hardness, and wear resistance. Improves fatigue resistance. |
| Titanium | Strongest carbide former. Added to stainless steel to prevent precipitation of chromium carbide. |
| Silicon | Removes oxygen in steel making. Improves toughness. Increases hardness ability |
| Boron | Increases hardenability. Produces fine grain size. |
| Aluminum | Forms nitride in nitriding steels. Produces fine grain size in casting. Removes oxygen in steel melting. |
| Cobalt | Increases heat and wear resistance. |
| Tungsten | Increases hardness at elevated temperatures. Refines grain size. |
Ceramic lined pipe is made through self-propagating high-temperature synthesis (SHS) technique.
Cast basalt lined steel pipe is composed by lined with cast basalt pipe, outside steel pipe and cement mortar filling between the two layers.
Ceramic tile lined pipes have very uniform coating of specially formulated ceramic material that is affixed to the inner of the pipe.
The material of the rare earth alloy wear-resistant pipe is ZG40CrMnMoNiSiRe, which is also the grade of rare earth alloy steel.
Tubes Erosion Shields are used to protect boiler tubing from the highly erosive effects of high temperatures and pressures thereby greatly extending tube life.
The ASTM A213 T91 seamless tubes are primarily used for boiler, superheater, and heat-exchanger.
